This is very minor.
(playground)
Expected output: "'"
Actual output: "\'"
Perhaps this was intentional, but I'm not sure why it would be. The closest issue I saw was #3752 which is ancient and was more obviously a bug since escapes were appearing in Display output and not just Debug.
This reproduces in the latest stable (1.50.0) and nightly (1.52.0-nightly) builds.